Prime Minister Sir Keir Starmer will push allies to provide Ukraine with more long-range missiles to strike Russian targets at a meeting in London on Friday.
He will host Ukrainian President Volodymyr Zelensky along with the so-called "coalition of the willing", comprising of more than 20 of Ukraine's allies who have agreed to provide Kyiv security guarantees once a ceasefire is brokered.
Zelensky has been pleading for weeks for more long-range weapons from the West, a move Russia has warned would escalate the conflict.
Ukraine's leader is travelling from Brussels, where he met EU leaders on Thursday seeking financial support.
Zelensky arrives off the back of two diplomatic wins this week: US President Donald Trump's decision to finally apply further sanctions against Russia, and the European Union agreeing to fund a Ukrainian budget hole.
