US and Russian officials will converge on the state of Alaska ahead of a highly anticipated Friday meeting between Presidents Donald Trump and Vladimir Putin.

The pair will meet for the first time in six years, as Trump tries to enact a key campaign pledge to end Russia's war in Ukraine.

The US president, who has portrayed himself as a global peacemaker, hopes to leverage his personal relationship with Putin to achieve a ceasefire breakthrough where others have failed.

On Thursday he assessed there was a "25% chance" the meeting would not be successful.

Ukraine's leader Volodymyr Zelensky has been excluded from the talks, and warned that any resolutions made in his absence will be meaningless.